The primary high gain effects used were the Sovtek Big Muff and a Proco Rat. Although it looks like a script logo Dunlop/MXR Dynacomp reissue, it is actually a vintage MXR Dynacomp from the 1970s with an LED and DC power jack added (the LED script reissue was not released until 2016). An MXR Dynacomp was also used for some clean tones, and to combine with the Boss CS-2 for some light overdrive rhythm, solos, and the Great Gig slide guitar. The heavier overdrive tones were mostly a Boss CS-2 into a Tube Driver set for medium drive. Most of the clean and overdrive solos were from a Boss CS-2 Compressor into a Tube Driver set for low drive. He feels that foot pedals such as a Big Muff tend to have more character - Phil Taylor, David Gilmour's guitar tech, Guitar World Sept 1994 I think his general feeling is that while rack effects tend to cover a lot of areas, they don't cover any of them particularly well.
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Butler Tube Drivers were used extensively for the main overdrive tones and to blend with the high gain effect pedals. Several new pedals were added, like the Russian made Sovtek Big Muff Pi and the Pete Cornish SS-2 Soft Sustain. The older TC BLD Booster, Ram's Head Big Muff, and Mesa/Boogie used in the Knebworth version of this rig were removed for the 1994 tour. 1994: Division Bell Tour and Pulse Live Lead Tones - ĮFFECT SETTINGS AND SIGNAL CHAINS - Although Gilmour's 1994 Pink Floyd tour rig seems more complex than his 1987-89 rig used for the previous Pink Floyd tour, the actual setups used seem to be more simplified.